Dave, I have used the Rustoleum 2X matte clear for sealing at least ten baits that I molded and had no curing issues with the silicone.
I do about 3 light to med coats and it doesn't seem to fill in much detail. Again, I normally say stay away from Rustoleum products, but this one has worked for me. I let the matte clear dry and off gas a few days in the sun
I have been using Smooth-On 29NV and Sprayway #946 Silicone release agent. I've always waited only and hour or two past the cure time to unmold the master.
Hope you get'r figured out...