This is the alloy I use https://www.rotometals.com/lead-free-bullet-casting-alloy-bismuth-based/. Tougher than pure bismuth or bismuth tin. Melts at a higher temp, pours at around *500. I started using this when I figured if it's togh enough for bullet casting, it's gotta be tough enough for jig making.
It is still brittle but not as brittle as other tin bismuth alloys. I have dropped some one the floor and had them crack. I also powder paint mine. I use an alcohol lamp and hold the jig over the flame for about 3-4 seconds then dip. Then to an oven around 200-250 degrees.
These are a PITA to remove from the mold!