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No, particle size does not matter. Dyes are soluble in plastisol where as pigments are not. If you think of it this way: -Pigments are like adding sand to water. Wont dissolve, wont move, the same as when you add it. -Dyes are like adding sugar to water. Will dissolve, will migrate to reach equilibrium. I know that is an oversimplification but it helps to conceptualize the difference between the two. Hope that helps.1 point