First of all, my best respects to those that are casting green. Yes, I too noticed that over heating bismuth, tin, or even lead will form excessive oxides aka slag. Still, I don't want to discourage anyone from discovering a better lead free alloy. I've tried to make tin "pewter" substituting 3-10% bismuth for antimony as a hardening agent, and all alloys were unsuitable for gravity pouring small round heads due to incomplete fill out, although larger size other styles managed with difficulty. R-92 would be a very hard nicely finishing lead free casting alloy, although as "Sagacious" mentions that alloy might be more suitable for pressure casting. "Fatman", are you gravity pouring R-92?
Prices of all casting metals continues to rise - $10 tin is history, unless you buy low grade slabs.