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goldenshinner

Understanding Chemisyry Of Heat Stabilizet

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Curious if anyone cares to contribute..is it true heat stabilizer acts by preventing free radicals chain reaction..much like adding absorbic acis(vitamin c).if so it will work for limited number of reheats and or only to such a point if an area got to hot its powr will be used up and plastic will show signs of damage.

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This my understanding of the chemistry, for what it's worth.

I think it has more to do with compound & molecule separation than smaller particles like free radicals.

Plastisol is made up of 3 components: Polyvinyl Chloride (same PVC pipe is made from) , Plasticizer, and Heat Stabilizer. There are a lot of different kinds of plasticizer and it's there to modify the PVC so it doesn't turn out as hard as pipe.

During the cooking process the PVC compound splits, producing and separating the vinyl and the chloride.

Without Heat Stabilizer the active chloride will (too) quickly re-bond with the vinyl causing the vinyl to discolor. So the heat stabilizer works by attaching to the chloride (technically the chloride salt) - a one time bonding process.

To much stabilizer will produce oily, stinky & inconsistent plastic. There is only so much chloride it can attach to so excess floating around in the mix will make the product unstable.

Reheating after the heat stabilizer is "used up" causes the rapid re-bonding of the vinyl & chloride, same as before, but the heat stabilizer is not available to slow things down. You may be able to add more but see the note about too much.

Ultimately, and obviously, the vinyl and chloride must reattach, but in a different final structure.

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This my understanding of the chemistry, for what it's worth.

I think it has more to do with compound & molecule separation than smaller particles like free radicals.

Plastisol is made up of 3 components: Polyvinyl Chloride (same PVC pipe is made from) , Plasticizer, and Heat Stabilizer. There are a lot of different kinds of plasticizer and it's there to modify the PVC so it doesn't turn out as hard as pipe.

During the cooking process the PVC compound splits, producing and separating the vinyl and the chloride.

Without Heat Stabilizer the active chloride will (too) quickly re-bond with the vinyl causing the vinyl to discolor. So the heat stabilizer works by attaching to the chloride (technically the chloride salt) - a one time bonding process.

To much stabilizer will produce oily, stinky & inconsistent plastic. There is only so much chloride it can attach to so excess floating around in the mix will make the product unstable.

Reheating after the heat stabilizer is "used up" causes the rapid re-bonding of the vinyl & chloride, same as before, but the heat stabilizer is not available to slow things down. You may be able to add more but see the note about too much.

Ultimately, and obviously, the vinyl and chloride must reattach, but in a different final structure.

 

From what I've been able to research, the ingredient list is a bit more involved but the same basic premise. 

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im surprised how little scientific information is available on this subject in this country. im sure a fair amount of research is public, just not easily accessible to most people. dow corning and dupont probably have a bunch of information, and if you could read Japanese im sure it would be amazing compared to what is known in this country. Japanese have researched everything, and its well organized. but impossible to get in this country. 

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